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Displacive
&
Diffusive Transformations
Displacive
Diffusive or diffusionless transformations occur by some
form of cooperative homogeneous movement of many atoms that results
in a change in crystal structure. These movements are small (usually
less than the interatomic distances) and the atoms maintain their relative
relationships (to their neighbours). The ordered movement of large numbers
of atoms lead some to refer to these as military transformations
The transformation involves, in this case, rows of many
atoms moving cooperatively.
Diffusive
Diffusive or reconstructive transformations require the
breaking and reforming of bonds. Reconstructive transitions are generally
very slow (they require bond breaking/vacancy diffusion) and can result
in a completely new atomic arrangement where the original neighbours
are not maintained
Click "move vacancy" to move the vacancy manually,
or use the run/stop buttons to run the simulation automatically
Comparing the position of the atoms after diffusive displacment shows
that neighbours are not maintained