Dissemination of IT for the Promotion of Materials Science (DoITPoMS)

DoITPoMS Micrograph Library Full Record for Micrograph 612

Full Record for Micrograph 612

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Micrograph no
612
Brief description
Nematic liquid crystalline polymer
Keywords
alignment, birefringence Link to MATTER Glossary entry for birefringence, disclination, liquid crystalline polymer (LCP), polymer Link to MATTER Glossary entry for polymer
Categories
Polymer
System
Liquid crystalline polymer
Composition
K24 (4-cyano-4'-8-alkylbiphenyl)
Standard codes
Reaction
N/A
Processing
Applications
Liquid crystalline polymers remain fluid whilst possessing long range order. This self-alignment enables the drawing of strong, stiff fibres such as Kevlar, as well as mouldable systems live Vectra. The response of LCPs to external fields is also useful in display technology
Sample preparation
A hot stage has been used to heat the LCP to over 35 degrees C
Technique
Cross-polarised light microscopy
Length bar
100 μm
Further information
Liquid crystalline polymers (LCPs) exhibit a mesophase above their melting temperature. In this phase, they are fluid yet they retain long-range orientational order. The self-alignment of crystallites manifests itself as patterns of optical birefringence when the liquids are viewed between crossed polars. Defects in the patterns are analogous to dislocations in crystal systems. This specimen is K24 (4-cyano-4'-8-alkylbiphenyl), which is nematic above 35 degrees C. The general gradation of colour is simply due to a wedge plate placed over the specimen.
Contributor
Prof T W Clyne
Organisation
Department of Materials Science and Metallurgy, University of Cambridge
Date
03/10/02
Licence for re-use
Attribution-NonCommercial-ShareAlike 4.0 International