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Peritectic: 21 wt.% Cu, 79 wt.% Sn
400μm
Click on regions of the micrograph for more information.
The epsilon phase precipitates out first. The precipitates
are visible in the micrograph as the phase surrounded by the paler eta
phase.
When the system goes below the peritectic temperature the
epsilon phase starts to transform to eta and new eta phase begins to
nucleate heterogeneously on the surface of the epsilon precipitates
The peritectic reaction (a solid plus liquid transforming
to another, different, solid) does not go to completion due to the new
phase creating a barrier to diffusion.
This prevents the composition of the system homogenising,
and so the remaining liquid phase is not of the bulk composition, and
so there is less eta than predicted by thermodynamics.