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Full Record for Micrograph 716

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Micrograph no
716
Brief description
IN718 nickel-based superalloy held for 3 hours at 850°C
Keywords
alloy Link to MATTER Glossary entry for alloy, metal, nickel, nickel-based superalloy, niobium, precipitation Link to MATTER Glossary entry for precipitation
Categories
Metal or alloy
System
Ni-X
Composition
Ni 53, Fe 19, Cr 18, Nb 5 (wt% approx) + small amounts of Ti, Mo, Co, Al
Standard codes
Reaction
Processing
Held for 3 hours at 850°C.
Applications
High temperature turbines.
Sample preparation
Grind on 240 grit SiC paper followed by polish on 9mm, 6mm, 1mm, and OPS.
Technique
Reflected light microscopy, cross-polarised, with Nomarski filter
Length bar
25 μm
Further information
IN718 is a nickel-based superalloy composed of approximately 53 wt% Ni, 19 wt% Fe, 18 wt% Cr, 5 wt% Nb, and small amounts of Ti, Mo, Co, and Al. The alloy has a number of distinct phases present in its microstructure. These are namely the matrix, g, and the precipitates, g', g'', and d.

The primary strengthening phase is g'' [1], the composition of which is Ni3Nb. It has a body-centred tetragonal structure, and forms semi-coherently as disc-shaped platelets within the g matrix, having three variants lying on the {100} planes. It is stable for over 10,000 hours at 600°C; however, above this temperature it decomposes to form g', Ni3Al (between 650°C and 850°C), and d, the same composition as g'' (between 750°C and 1000°C). It has been commented that, at large volume fractions and when it forms continuously along grain boundaries, d is detrimental to both strength and toughness [2].

The d phase that forms is more stable than the g'' phase, and has an orthorhombic structure. During cooling, d phase precipitates begin to form along the {111} planes in the matrix, nucleating at grain boundaries at approximately 1010°C.

The g' precipitates, of L12 structure, are seen within the g matrix when it has been depleted of niobium due to the formation of g'' and d.

The Time-Temperature-Transformation (TTT) diagram for IN718 shows that d precipitates at higher temperatures than the g'', and that over long periods of time both d and g' are more stable than g''.

The micrograph shows the microstructure after being held for 3 hours at 850°C, the volume fraction of d is greater than when held for shorter periods of time.

References:

[1] J. W. Brooks and P. J. Bridges. Metallurgical Stability of Inconel Alloy 718. Superalloys '88, pages 33 - 42, 1988.
[2] B. Gleeson. High-Temperature Corrosion of Metallic Alloys and Coatings: Volume II. In M. Schütze, editor, Corrosion and Environmental Degradation, volume 19 of Materials Science and Technology, chapter 5, pages 173 - 228. Wiley, 2000.

Contributor
R Guest
Organisation
Rolls-Royce University Technology Centre, Department of Materials Science and Metallurgy, University of Cambridge
Date
28/01/03
Licence for re-use
Attribution-Non-Commercial-Share Alike 2.0 UK: England & Wales
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