
Gold’s Pourbaix diagram explains why it is the most immune substance known. It is immune in all regions in which cathodic reactions can take place. So gold never* corrodes in an aqueous environment.
Immunity of aluminium only occurs at lower potentials. Therefore, unless under conditions that cause it to passivate, it is much more susceptible to corrosion than gold or zinc.
* provided that the water is pure; that no ion complexes are present to provide a cathodic half cell reaction that occurs at a potential higher than +1.5 V(SHE).
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